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Öğe The performance of UNIFAC and related group contribution models .1. Prediction of infinite dilution activity coefficients(Elsevier, 1996) Paksoy, HO; Ornektekin, S; Balcl, B; Demirel, YInfinite dilution activity coefficients have been calculated for 24 systems including highly non-ideal and nearly non-ideal using original, modified UNIFAC and UNIFAC-FV models. The calculations are compared with experimental results. The performance of the models in predictions and the significance of free volume effects on solvent activities in solutions containing small compounds are discussed.Öğe The performance of UNIFAC and related group contribution models .2. Prediction of Henry's law constants(Elsevier, 1996) Ornektekin, S; Paksoy, HO; Demirel, YHenry's law constants for 24 different systems have been determined using UNIFAC and related group contribution models. The results obtained from original, modified and free-volume effect UNIFAC models are compared with experimental results, Empirical relationships for the temperature-dependency of Henry's constant for the chloroform(1)-water(2) system are also determined.
