Li:Ce co-doped CdO films synthesized by SILAR method: Effects of rare earth element Ce content on the physical attributes
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Dosyalar
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Sci Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Undoped, Li-doped (Li0.02Cd0.98O) and Li:Ce co-doped (Ce-x Li0.02Cd0.98-xO (x = 0.005, 0.01 and 0.02)) CdO nanofilms were prepared by a successive ionic layer adsorption and reaction (SILAR) process. The effects of the Li and Li:Ce doping on the main physical properties such as crystal structure, surface morphological characteristics and optical features like bandgap and transmittance of obtained these films were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and UV-Vis spectrophotometer respectively. X-ray diffractogram analysis verified that the synthesized CdO films pertain to the cubic structure. XRD analysis indicated the growth of CdO with polycrystalline form for preferential orientation along the (111) and (200) plane. It is obviously seen from the SEM micrographs that Li doping and Li:Ce co-doping induce remarkable changes in the CdO surface morphology. The UV-Vis spectroscopy analysis results show that the (2.0% Li + 1.0% Ce) Li:Ce co-doped CdO films exhibits maximum transmittance (27%) in the range between 300 and 1100 nm and high optical bandgap energy (E-g = 2.92 eV).
Açıklama
Anahtar Kelimeler
Rare earth element, Co-doping, Ce, CdO, SILAR
Kaynak
Ceramics International
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
44
Sayı
18