Alternative Approach for Synthesizing Polyglycolic Acid Copolymers from Cl Feedstocks and Fatty Ester Epoxides

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dc.authoridSahmetlioglu, Ertugrul/0000-0002-7324-0385
dc.authoridGokturk, ersen/0000-0001-6742-2847
dc.contributor.authorReyhanoglu, Yusuf
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorGokturk, Ersen
dc.date.accessioned2024-09-18T20:54:21Z
dc.date.available2024-09-18T20:54:21Z
dc.date.issued2019
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractOver the past couple of years, replacement of petroleum-based products with biodegradable and biorenewable is an emerging topic in polymer science. Biodegradable polyglycolic acid (PGA), the simplest aliphatic linear polyester, can traditionally be synthesized through the ring-opening polymerization of glycolide. Our previous studies revealed that PGA can alternatively be produced via one-step cationic polymerization of formaldehyde from trioxane and carbon monoxide (CO), which are potentially sustainable C1 feedstocks, under Bronsted acidic conditions. In this study, trioxane, CO, and a minor amount of fatty ester epoxides are copolymerized to improve on the physical properties of PGA, such as solubility and appearance, under the same reaction conditions for PGA homopolymer synthesis (in DCM, at 800 psi CO, with triflic acid catalyst, reaction duration of 72 h). The results have shown that the addition of minor quantities of epoxide comonomers vastly improved the solubility and decreased the melting temperature of the PGA. The melting temperatures of the obtained copolymers decreased by increasing incorporation percentages of the epoxide comonomers and decreasing polymerization temperatures. The solubility of the copolymers increased with incorporation of the epoxides in the PGA backbone.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [115Z482]en_US
dc.description.sponsorshipThis study was funded by The Scientific and Technological Research Council of Turkey (TUBITAK), 3501-Career Development Program via grant number 115Z482. We also thank Dr. Basri Gulbakan and Dr. Ilker Avan for their proofreading.en_US
dc.identifier.doi10.1021/acssuschemeng.8b05940
dc.identifier.endpage5110en_US
dc.identifier.issn2168-0485
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85062431125en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage5103en_US
dc.identifier.urihttps://doi.org/10.1021/acssuschemeng.8b05940
dc.identifier.urihttps://hdl.handle.net/20.500.12483/11765
dc.identifier.volume7en_US
dc.identifier.wosWOS:000460600500058en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofAcs Sustainable Chemistry & Engineeringen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolyglycolic aciden_US
dc.subjectFormaldehydeen_US
dc.subjectCarbon monoxideen_US
dc.subjectFatty acidsen_US
dc.subjectEpoxideen_US
dc.subjectCationic polymerizationen_US
dc.titleAlternative Approach for Synthesizing Polyglycolic Acid Copolymers from Cl Feedstocks and Fatty Ester Epoxidesen_US
dc.typeArticleen_US

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