Solution dynamics of the dextran/crosslinking agent systems

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dc.contributor.authorOzdemir, Cemile
dc.contributor.authorColak, Nureddin
dc.contributor.authorGuner, Ali
dc.date.accessioned2024-09-18T20:15:07Z
dc.date.available2024-09-18T20:15:07Z
dc.date.issued2007
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractThe interaction of some selective Cl- and Ncontaining functional crosslinking agents such as epichlorohydrin (ECH), N,N'-methylenebisacrylamide (MBAM), and bifunctional agents such as glutaraldehyde (GA) and glycidylmethacrylate (GM) with dextran (Dx) in aqueous solutions were studied by viscometric and spectroscopic methods. The dynamic viscosities of Dx-crosslinker aqueous solutions have been measured at physiological temperature, 37 degrees C and in the concentration range of 0.220.4 g/dL. Concentration of crosslinkers were kept constant at 0.001-0.35 mol/L. Viscosity behavior of the solutions was interpreted using the Huggins and Kraemer equations. Moreover, the interaction between hydroxyl groups of the Dx with crosslinkers in aqueous solutions, structure properties was also confirmed thereby use of Raman and FTIR spectroscopy. For the Dx/crosslinker systems, the decreasing order of interaction was determined as ECH > GA > MBAM > GM. (c) 2007 Wiley Periodicals, Inc.en_US
dc.identifier.doi10.1002/app.25900
dc.identifier.endpage1187en_US
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-34547463491en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1177en_US
dc.identifier.urihttps://doi.org/10.1002/app.25900
dc.identifier.urihttps://hdl.handle.net/20.500.12483/9463
dc.identifier.volume105en_US
dc.identifier.wosWOS:000247576000021en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectdextran/water/crosslinker systemen_US
dc.subjectviscometryen_US
dc.subjectsolution dynamicsen_US
dc.subjectFTIR spectroscopyen_US
dc.subjectRaman spectroscopyen_US
dc.titleSolution dynamics of the dextran/crosslinking agent systemsen_US
dc.typeArticleen_US

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