Optical and Morphological Properties of New Metallophthalocyanines with Hydroxyethylsulfanyl Substituents
Yükleniyor...
Tarih
2019
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Maik Nauka/Interperiodica/Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Metallophthalocyanine complexes (M = Pd, FeCl, VO, or MnCl) bearing four hydroxyl-terminated aliphatic groups were prepared by cyclotetramerization 4-(hydroxyethylsulfanyl)phthalonitrile. Aggregation tendencies of these phthalocyanines were investigated in varying concentrations from 4 x 10(-5) to 8 x 10(-6) M in DMF. Spin coating method was used to prepare thin films of metallophthalocyanines substituted with four hydroxyethylsulfanyl groups. The optical properties of the films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 200-1000 nm. The results show that different metal ions in the inner core clearly change the transmittance values of the thin films of metallophthalocyanine. Morphological results also show that surface of the metallophthalocyanines has changed considerably according to the nature of the metal ion.
Açıklama
Anahtar Kelimeler
metallophthalocyanine, hydroxyethylsulfanyl groups, synthesis, optical properties, morphological properties
Kaynak
Protection of Metals and Physical Chemistry of Surfaces
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
55
Sayı
5
