Immobilization of salophen derivative Schiff base cobalt(II) complex on a copolymer coated platinum electrode and electrocatalytic investigations

Basit Öğe Kaydı
dc.contributor.authorCakmak, D.
dc.contributor.authorYalcinkaya, S.
dc.contributor.authorSeymen, K.
dc.contributor.authorDemetgul, C.
dc.date.accessioned2024-09-18T20:52:49Z
dc.date.available2024-09-18T20:52:49Z
dc.date.issued2016
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractIn this study, o-amino-benzylalcohol (pBA) and o-anisidine (pA) homopolymers and their copolymer (o-aminobenzylalcohol- co-o-anisidine) (Cp) were synthesized on the platinum electrode in 0.5 M H2SO4 as a supporting electrolyte medium by electrochemical methods. Then, Co(II) complex of salophen type Schiff base (CoL) was immobilized on these polymer coated electrode surfaces in acetonitrile containing 0.15 M LiClO4. The prepared modified surfaces were characterized by Cyclic Voltammetry, UV-Vis, SEM-EDAX and ICP-MS techniques. The electrocatalytic activity of modified electrodes was investigated on electrooxidation of Dopamine (DA) as biosensor application. One of the prepared modified electrodes showed good electrocatalytic effect on the oxidation of DA using Square Wave Voltammetry method (SWV). The oxidation peak current of DA increased linearly in the range of 0.2 mu M - 2 mM in pH 7 phosphate buffer solution at left perpendicular CoL right perpendicular immobilized pA modified Platinum electrode. Limit of Detection (LOD) was calculated as 0.1 mu M for DA determination.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [114Z691]en_US
dc.description.sponsorshipThis Project was supported by The Scientific and Technological Research Council of Turkey (Project Number: 114Z691)en_US
dc.identifier.endpage61en_US
dc.identifier.issn0324-1130
dc.identifier.startpage55en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12483/11420
dc.identifier.volume48en_US
dc.identifier.wosWOS:000392342400011en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherBulgarian Acad Scienceen_US
dc.relation.ispartofBulgarian Chemical Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjecto-amino-benzyl alcoholen_US
dc.subjectelectropolymerizationen_US
dc.subjectSchiff Base metal complexen_US
dc.subjectimmobilizationen_US
dc.subjectelectrocatalytic investigationen_US
dc.titleImmobilization of salophen derivative Schiff base cobalt(II) complex on a copolymer coated platinum electrode and electrocatalytic investigationsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu