Hydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Ability

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dc.authoridOlukman Sahin, Merve/0000-0002-9588-2661
dc.contributor.authorOlukman Sahin, Merve
dc.contributor.authorDemirbilek Bucak, Celile
dc.date.accessioned2024-09-18T20:26:54Z
dc.date.available2024-09-18T20:26:54Z
dc.date.issued2023
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractIn this study, hydrophobic modified poly(acrylamide/octadecyl acrylate) (poly(AAm/C18)) and poly(acrylamide/octadecyl acrylate)-carboxymethyl cellulose (poly(AAm/C18)-CMC) hydrogels with high mechanical strength and shape memory properties were synthesized by random copolymerization method. Hydrogel synthesis was successfully carried out in one step on the basis of the hydrophobic monomer units carrying alkyl side chains included in the hydrophilic polymer network, and these hydrophobes clustered in water and acted as crosslinks. Hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), Differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and X-ray diffractometry (XRD). The results showed that with the increase of the amount of hydrophobic monomer (C18) in the hydrogels, the crystal regions in the hydrogel structure increased. The swelling behaviour of the hydrogels was investigated as a function of the hydrophobic monomer content. Experimental swelling data confirmed the DSC and XRD results. The shape memory properties of hydrogels containing CMC were investigated. The new shape of the hydrogels was fixed by complexation between CMC and metal (M2+ and M3+ valence) ions.en_US
dc.description.sponsorshipScientific Research Projects Coordination Unit of Hatay Mustafa Kemal University [20.M.057]; Hatay Mustafa Kemal University [20.M.057]en_US
dc.description.sponsorshipScientific Research Projects Coordination Unit of Hatay Mustafa Kemal University [Project number: 20.M.057]. Hatay Mustafa Kemal University, 20.M.057, 20.M.057en_US
dc.identifier.doi10.1007/s10924-023-02807-z
dc.identifier.endpage3663en_US
dc.identifier.issn1566-2543
dc.identifier.issn1572-8919
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-85151494470en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage3650en_US
dc.identifier.urihttps://doi.org/10.1007/s10924-023-02807-z
dc.identifier.urihttps://hdl.handle.net/20.500.12483/10587
dc.identifier.volume31en_US
dc.identifier.wosWOS:000963019200001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Polymers and The Environmenten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHydrogelsen_US
dc.subjectShape memoryen_US
dc.subjectHydrophobic associationen_US
dc.subjectSwelling behaviouren_US
dc.titleHydrophobically Associated Poly(acrylamide/octadecyl acrylate)-Carboxymethyl Cellulose Hydrogels: Synthesis, Characterization, and Shape Memory Abilityen_US
dc.typeArticleen_US

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