Synthesis and characterization of poly(m-aminophenol)-succinat

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dc.contributor.authorDinc, Cemile Ozdemir
dc.contributor.authorYalcinkaya, Suleyman
dc.contributor.authorAltuntas, Hazal
dc.contributor.authorColak, Nureddin
dc.date.accessioned2024-09-18T20:19:53Z
dc.date.available2024-09-18T20:19:53Z
dc.date.issued2014
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractPoly(m-aminophenol) (PMAP) and poly(m-aminophenol)-succinat compound (PMAP-Suc) containing ester bridge were synthesized in this study. PMAP were synthesized by chemical oxidative polymerization of m-aminophenol (MAP) in HCl medium with ammonium peroxydisulphate (APS) as an initiator at different temperatures. The optimum polymerization conditions (temperature: 25 degrees C, reaction time: 4 h, normalized MAP/APS ratio, k: 0.625 and mol of MAP/mol of APS, r: 0.5) of PMAP were determined. PMAP was esterified in N-methyl pyrrolidone by using solution of succinic acid as cross-linking agent and concentrated sulphuric acid as catalyst under appropriate ambient conditions. The general scheme of esterification and cross-linking reaction for PMAP is proposed. These reactions were also evidenced by spectroscopic, thermal and surface morphology as well as structural characteristics relationship of macromolecules. The structures of PMAP and PMAP-Suc were characterized by solubility test, FTIR, H-1 NMR and C-13 NMR, UV-vis spectroscopy, thermal (TGA-DTA) and SEM analyses.en_US
dc.description.sponsorshipScientific Research Project Unit (BAP) of Mustafa Kemal University [1001-Y-0102]en_US
dc.description.sponsorshipThe authors gratefully thank Scientific Research Project Unit (BAP) of Mustafa Kemal University (1001-Y-0102) for the financial support and Burak Ay for providing FTIR spectra in this work.en_US
dc.identifier.doi10.1080/15685551.2014.907617
dc.identifier.endpage636en_US
dc.identifier.issn1385-772X
dc.identifier.issn1568-5551
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84899961407en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage629en_US
dc.identifier.urihttps://doi.org/10.1080/15685551.2014.907617
dc.identifier.urihttps://hdl.handle.net/20.500.12483/9927
dc.identifier.volume17en_US
dc.identifier.wosWOS:000335089300005en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofDesigned Monomers and Polymersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectesterificationen_US
dc.subjectsuccinic aciden_US
dc.subjectester bridgeen_US
dc.subjectcross-linkingen_US
dc.subjectpoly(m-amino phenol)en_US
dc.titleSynthesis and characterization of poly(m-aminophenol)-succinaten_US
dc.typeArticleen_US

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