Synthesis, characterization, and comparison of self doped, doped, and undoped forms of polyaniline, poly(o-anisidine), and poly[aniline-co-(o-anisidine)]
| dc.contributor.author | Özdemir, C | |
| dc.contributor.author | Can, HK | |
| dc.contributor.author | Çolak, N | |
| dc.contributor.author | Güner, A | |
| dc.date.accessioned | 2024-09-18T20:11:45Z | |
| dc.date.available | 2024-09-18T20:11:45Z | |
| dc.date.issued | 2006 | |
| dc.department | Hatay Mustafa Kemal Üniversitesi | en_US |
| dc.description.abstract | Polyaniline (PANI), poly(o-anisidine), and poly[aniline-co-(o-anisidine)] were synthesized by chemical oxidative polymerization with ammonium persulfate as an oxidizing reagent in an HCl medium. The viscosities, electrical conductivity, and crystallinity of the resulting polymers (self-doped forms) were compared with those of the doped and undloped forms. The self-doped, doped, and undoped forms of these polymers were characterized with infrared spectroscopy, ultraviolet-visible spectroscopy, and a four-point-probe conductivity method. X-ray diffraction characterization revealed the crystalline nature of the polymers. The observed decrease in the conductivity of the copolymer and poly(o-anisidine) with respect to PANI was attributed to the incorporation of the methoxy moieties into the PANI chain. The homopolymers attained conductivity in the range of 3.97 X 10(-3) to 7.8 S/cm after doping with HCl. The conductivity of the undoped forms of the poly[aniline-co-(o-anisidine)] and poly(o-anisidine) was observed to be lower than 10(-5) J/S cm(-1). The conductivity of the studied polymer forms decreased by the doping process in the following order: self-doped -> doped -> undoped. The conductivity of the studied polymers decreased by the monomer species in the following order: PANI -> poly[aniline-co(o-anisidine)] -> poly(o-anisidine). All the polymer samples were largely amorphous, but with the attachment of the pendant groups of anisidine to the polymer system, the crystallinity region increased. The undoped form of poly [aniline-co-(o-anisidine)] had good solubility in common organic solvents, whereas doped poly [aniline-co-(oanisidine)] was moderately crystalline and exhibited higher conductivity than the anisidine homopolymer. | en_US |
| dc.identifier.doi | 10.1002/app.22718 | |
| dc.identifier.endpage | 2192 | en_US |
| dc.identifier.issn | 0021-8995 | |
| dc.identifier.issn | 1097-4628 | |
| dc.identifier.issue | 5 | en_US |
| dc.identifier.scopus | 2-s2.0-33644544398 | en_US |
| dc.identifier.scopusquality | Q2 | en_US |
| dc.identifier.startpage | 2182 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/app.22718 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12483/9054 | |
| dc.identifier.volume | 99 | en_US |
| dc.identifier.wos | WOS:000235099200026 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Wiley | en_US |
| dc.relation.ispartof | Journal of Applied Polymer Science | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | conducting polymers | en_US |
| dc.subject | infrared spectroscopy | en_US |
| dc.subject | solution properties | en_US |
| dc.subject | UV-vis spectroscopy | en_US |
| dc.subject | X-ray | en_US |
| dc.title | Synthesis, characterization, and comparison of self doped, doped, and undoped forms of polyaniline, poly(o-anisidine), and poly[aniline-co-(o-anisidine)] | en_US |
| dc.type | Article | en_US |
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