Synthesis, characterization and antimicrobial activities of some metal complexes with N?-(2-chloro-benzoyl)thiourea ligands

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dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridKulcu, Nevzat/0000-0002-6678-1036
dc.contributor.authorEmen, MF
dc.contributor.authorArslan, H
dc.contributor.authorKülcü, N
dc.contributor.authorFlörke, U
dc.contributor.authorDuran, N
dc.date.accessioned2024-09-18T20:59:24Z
dc.date.available2024-09-18T20:59:24Z
dc.date.issued2005
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractWe report the synthesis, structural characterization and antimicrobial activities of N,N-dimethyl-N'-(2-chloro-benzoyl)thiourea ((LH)-H-1) and N-pyrrolidine-N'-(2-chlorobenzoyl)thiourea ((LH)-H-2) and their Ni(II), Cu(II), Zn(II), Pt(II), Pd(II) and Co(III) complexes. The structure of the prepared compounds was investigated by using elemental analyses, IR, H-1-NMR, UV-Vis, mass spectra and magnetic susceptibility. The prepared compounds were screened for their in vitro antibacterial and antifungal activities. All compounds showed antimicrobial activity, however, the antibacterial efficacy is better than antifungal activity. Molecular structures of Co(L-1)(3) and Pd(L-1)(2) were determined by single crystal X-ray diffraction methods. The ligands coordinate to Ni(II), Cu(II), Zn(II), Pt(II) and Pd(II) in a bidentate manner yielding essentially neutral complexes of the type ML2. The coordination polyhedra around the Co(III) ion are distorted octahedra.en_US
dc.identifier.endpage1626en_US
dc.identifier.issn0137-5083
dc.identifier.issue10en_US
dc.identifier.startpage1615en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12555
dc.identifier.volume79en_US
dc.identifier.wosWOS:000232589600007en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherPolish Chemical Socen_US
dc.relation.ispartofPolish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectthioureasen_US
dc.subjectsynthesisen_US
dc.subjectX-ray structureen_US
dc.subjectantimicrobial activitiesen_US
dc.subjectbenzoylthiourea complexesen_US
dc.titleSynthesis, characterization and antimicrobial activities of some metal complexes with N?-(2-chloro-benzoyl)thiourea ligandsen_US
dc.typeArticleen_US

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