Electropolymerization of CuII-(N,N?-bis(3-methoxysalicylidene)-2-aminobenzylamine) on platinum electrode: Application to the electrocatalytic reduction of hydrogen peroxide

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dc.authoridtimur, mahir/0000-0001-5914-607X
dc.authoridgonul, ilyas/0000-0002-7697-3613
dc.authoridDEMETGUL, CAHIT/0000-0003-1559-7279
dc.contributor.authorDeletioglu, Didem
dc.contributor.authorYalcinkaya, Suleyman
dc.contributor.authorDemetgul, Cahit
dc.contributor.authorTimur, Mahir
dc.contributor.authorSerin, Selahattin
dc.date.accessioned2024-09-18T20:28:00Z
dc.date.available2024-09-18T20:28:00Z
dc.date.issued2011
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractThe complex of copper (II) with N,N'-bis(3-methoxysalicylidene)-2-aminobenzylamine (H2L) was synthesized and characterized by elemental analysis, magnetic susceptibility, UV-vis. and FT-IR spectroscopy. The results showed that the tetradentate ligand coordinated to the Cu(II) ion through the azomethine nitrogen and phenolic oxygen atoms. The prepared complex [CuL] was electropolymerized on platinum electrode surface in a 0.1 mol dm(-3) solution of lithium perchlorate in acetonitrile by cyclic voltammetry between 0 and 1.6V vs. Ag/Ag+. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), conductance measurements, FT-IR and SEM were used to characterize polymer film of Cu(II) complex. The reduction of hydrogen peroxide on poly[CuL] has been investigated mainly in phosphate buffer medium (pH 7.2), between 0 and -0.8 V versus Ag/Ag+ at a scan rate 0.1 V s(-1). (c) 2011 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.matchemphys.2011.03.050
dc.identifier.endpage506en_US
dc.identifier.issn0254-0584
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-79957923845en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage500en_US
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2011.03.050
dc.identifier.urihttps://hdl.handle.net/20.500.12483/10667
dc.identifier.volume128en_US
dc.identifier.wosWOS:000292230800031en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofMaterials Chemistry and Physicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectInorganic compoundsen_US
dc.subjectElectrochemical techniquesen_US
dc.subjectElectrochemical propertiesen_US
dc.subjectPolymersen_US
dc.subjectElectrocatalytic reductionen_US
dc.subjectHydrogen peroxideen_US
dc.subjectSchiff base-copper (II) complexen_US
dc.titleElectropolymerization of CuII-(N,N?-bis(3-methoxysalicylidene)-2-aminobenzylamine) on platinum electrode: Application to the electrocatalytic reduction of hydrogen peroxideen_US
dc.typeArticleen_US

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