Poly(2-chloroaniline) and poly(aniline-co-2-chloroaniline) films on ZnFe alloy plating

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dc.authoridAKDAG, ABDURRAHMAN/0000-0001-5292-8001
dc.contributor.authorAkdag, Abdurrahman
dc.contributor.authorOzyilmaz, Gul
dc.contributor.authorOzyilmaz, Ali Tuncay
dc.date.accessioned2024-09-18T20:13:23Z
dc.date.available2024-09-18T20:13:23Z
dc.date.issued2018
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractPurpose The purpose of this paper is to evaluate and compare the protective, anticorrosion behaviors and electrochemically synthesis of poly(2-chloroaniline) (PCANI) and poly(2-chloroaniline-co-aniline) P(CANI-co-ANI) films on thin zinc-iron plated carbon steel (CS). Design/methodology/approach Zinc-iron (ZnFe) alloy plating was successfully achieved on CS applying 3 mA constant current value. The PCANI and P(CANI-co-ANI) films on ZnFe-plated CS electrode were synthesized by cyclic voltammetry technique using monomer(s) containing 0.20 M sodium oxalate solution. The CS/ZnFe electrodes with and without PCANI or P(CANI-co-ANI) films were characterized using SEM and anodic linear sweep voltammograms. The anticorrosive behaviors of uncoated and coated electrodes were studied in 3.5 per cent NaCl solution by corrosion techniques which include open circuit potential measurements, the anodic polarization curves and alternative current electrochemical impedance spectroscopy (EIS) technique. Findings The protection efficiency values (E per cent) for CS/ZnFe, ZnCS/ZnFe/PCANI and CS/ZnFe/P(CANI-co-ANI) electrodes were calculated as 71.05, 84.53 and 92.79, respectively, after 168 h of immersion time. The results showed that P(CANI-co-ANI) coating on ZnFe-plated CS electrode exhibited higher corrosion resistance and provided better barrier property in comparison with PCANI coating and ZnFe alloy plating, in longer exposure time. Originality/value A number of reports on the synthesis and characterization of PANI have appeared in the literature during the past decade, but there is no such publication of PCANI. At the same time, the synthesis of PCANI onto the surface of metal alloy coating being the first of this kind, no such proceedings have been reported in the literature so far.en_US
dc.identifier.doi10.1108/ACMM-04-2018-1922
dc.identifier.endpage586en_US
dc.identifier.issn0003-5599
dc.identifier.issn1758-4221
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85053560281en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage580en_US
dc.identifier.urihttps://doi.org/10.1108/ACMM-04-2018-1922
dc.identifier.urihttps://hdl.handle.net/20.500.12483/9142
dc.identifier.volume65en_US
dc.identifier.wosWOS:000448724400007en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherEmerald Group Publishing Ltden_US
dc.relation.ispartofAnti-Corrosion Methods and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCorrosionen_US
dc.subjectElectrochemistryen_US
dc.subjectSurface preparationen_US
dc.subjectCoatings and liningsen_US
dc.subjectNon-metallics plastics anden_US
dc.subjector polymersen_US
dc.titlePoly(2-chloroaniline) and poly(aniline-co-2-chloroaniline) films on ZnFe alloy platingen_US
dc.typeArticleen_US

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