Spectroscopic, electrochemical and optical properties of non-peripherally (2,2-dimethyl-1,3-dioxolan-4-yl)methoxy groups substituted metal-free and metallophthalocyanines

Basit Öğe Kaydı
dc.authoridSORAR, IDRIS/0000-0002-1082-7576
dc.authoridOzcesmeci, Mukaddes/0000-0002-6723-6902
dc.authoridGumrukcu, Selin/0000-0002-3135-6590
dc.contributor.authorTagman, Irem
dc.contributor.authorOzcesmeci, Mukaddes
dc.contributor.authorGumrukcu, Selin
dc.contributor.authorSorar, Idris
dc.date.accessioned2024-09-18T20:54:14Z
dc.date.available2024-09-18T20:54:14Z
dc.date.issued2021
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractMetal-free and metallophthalocyanine complexes (M = 2H, InCl, or MnCl) containing (2,2-dimethyl-1,3dioxolan-4-yl)methoxy groups were synthesized and characterized. The electrochemical properties of the phthalocyanine complexes were investigated by cyclic and square wave voltammetry. Metal-free and indium phthalocyanines give ring-based oxidation and reduction processes, while manganese phthalocyanine gives both metal and ring-based redox processes. Thin films of phthalocyanines were prepared by spin coating technique. The films were investigated as a function of the different metal ions in the inner core, with the transmittance spectrum measured at a wavelength range of 20 0-10 0 0 nm. The results show that type of metal ions in the phthalocyanine core clearly change the transmittance values of the thin films of phthalocyanine complexes. Surface morphologies of the films were characterized by scanning electron microscopy. It has been observed that metal-free films form a more continuous and non-porous structure, while InPc and MnPc films have a porous surface. (c) 2021 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipResearch Fund of the Istanbul Technical Universityen_US
dc.description.sponsorshipThis work was supported by the Research Fund of the Istanbul Technical University.en_US
dc.identifier.doi10.1016/j.molstruc.2021.131045
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85109914133en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2021.131045
dc.identifier.urihttps://hdl.handle.net/20.500.12483/11694
dc.identifier.volume1245en_US
dc.identifier.wosWOS:000709551000015en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhthalocyanineen_US
dc.subjectSpin coatingen_US
dc.subjectThin filmen_US
dc.subjectOptical propertiesen_US
dc.subjectCyclic voltammetryen_US
dc.titleSpectroscopic, electrochemical and optical properties of non-peripherally (2,2-dimethyl-1,3-dioxolan-4-yl)methoxy groups substituted metal-free and metallophthalocyaninesen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ N/A ]
İsim:
Tam Metin / Full Text
Boyut:
1.11 MB
Biçim:
Adobe Portable Document Format
İndir

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu