Novel synthesis medium for poly(aniline-co-o-anisidine)
| dc.contributor.author | Ozyilmaz, A. T. | |
| dc.contributor.author | Ozyilmaz, G. | |
| dc.contributor.author | Colak, N. | |
| dc.date.accessioned | 2024-09-18T20:13:23Z | |
| dc.date.available | 2024-09-18T20:13:23Z | |
| dc.date.issued | 2006 | |
| dc.department | Hatay Mustafa Kemal Üniversitesi | en_US |
| dc.description.abstract | Aqueous sodium oxalate (NaOX) solutions both without (1) and with (2) p-toluenesulfonic acid (p-TSA) were used to synthesize a poly (aniline-co-o-anisidine) (PANI-co-POA) film on mild steel (MS). Polarization of the substrate in p-TSA containing NaOX solution mixture led to the passivation of the surface mainly via the formation of an iron(II) oxalate layer. Copolymer coatings showed that p-TSA+NaOX solution mixture was a suitable medium for the deposition of a uniform, compact and strongly adherent PANI-co-POA coating on MS electrode. Similar coating was achieved when NaOX solution was used free of p-TSA. It was observed that addition of p-TSA in NaOX solution provided also an increase in electropolymerization rate. Evaluation of the anticorrosion performance of copolymer coatings in 3.5% NaCl solution was investigated by using AC impedance spectroscopy (EIS) technique and anodic polarization curves. Both copolymer coatings exhibited a significant physical barrier property against the attack of corrosive products on mild steel, in longer periods. (c) 2006 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.surfcoat.2006.04.008 | |
| dc.identifier.endpage | 2490 | en_US |
| dc.identifier.issn | 0257-8972 | |
| dc.identifier.issue | 6 | en_US |
| dc.identifier.scopus | 2-s2.0-33750982112 | en_US |
| dc.identifier.scopusquality | Q1 | en_US |
| dc.identifier.startpage | 2484 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/j.surfcoat.2006.04.008 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12483/9145 | |
| dc.identifier.volume | 201 | en_US |
| dc.identifier.wos | WOS:000244831800050 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science Sa | en_US |
| dc.relation.ispartof | Surface & Coatings Technology | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | corrosion | en_US |
| dc.subject | impedance spectroscopy | en_US |
| dc.subject | copolymer | en_US |
| dc.subject | monolayer | en_US |
| dc.subject | mild steel | en_US |
| dc.subject | electrolyte solution | en_US |
| dc.title | Novel synthesis medium for poly(aniline-co-o-anisidine) | en_US |
| dc.type | Article | en_US |
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