Electropolymerization and characterization of salophen derivative Schiff base Co(II) and Ni(II) complexes on the graphite electrode and electrocatalytic investigations

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dc.contributor.authorCakmak, D.
dc.contributor.authorBulut, T.
dc.date.accessioned2024-09-18T20:56:51Z
dc.date.available2024-09-18T20:56:51Z
dc.date.issued2017
dc.departmentHatay Mustafa Kemal Ãœniversitesien_US
dc.description3rd International Conference on New Trends in Chemistry -- APR 28-30, 2017 -- Helsinki, FINLANDen_US
dc.description.abstractIn this study, pencil graphite electrode surfaces were modified with Salophen derivative Schiff base Co(II)and Ni(II) complexes. Surface modification procedure was carried out by electrochemical oxidation method at 0.0-2.0 V potential range in acetonitrile containing 0.15 M LiClO4 as a supporting electrolyte medium. The prepared modified surfaces were characterized by cyclic voltammetry, EIS, FT-IR UV-Vis and SEM/SEM-EDX techniques. Modification of surfaces was confirmed by results of characterization studies. The electrocatalytic activity of modified electrodes was investigated upon bioanalytical species like ascorbic acid, catechol, cysteine etc. It was seen that both modified electrodes showed excellent electrocatalytic activity on catechol, but the catalytic activity potential of the electrode modified with Co (II) complex was higher on the other species.en_US
dc.description.sponsorshipScientific Research Projects Committee of Mustafa Kemal University [15101]en_US
dc.description.sponsorshipThis study is supported by Scientific Research Projects Committee of Mustafa Kemal University (Project number: 15101).en_US
dc.identifier.endpage36en_US
dc.identifier.issn0324-1130
dc.identifier.startpage30en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12132
dc.identifier.volume49en_US
dc.identifier.wosWOS:000413538600005en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherBulgarian Acad Scienceen_US
dc.relation.ispartofBulgarian Chemical Communicationsen_US
dc.relation.publicationcategoryKonferans Öğesi - Uluslararası - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Base metal complexen_US
dc.subjectelectropolymerizationen_US
dc.subjectsurface characterizationen_US
dc.subjectelectrocatalytic investigationen_US
dc.titleElectropolymerization and characterization of salophen derivative Schiff base Co(II) and Ni(II) complexes on the graphite electrode and electrocatalytic investigationsen_US
dc.typeConference Objecten_US

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