Electrochemical synthesis of poly(pyrrole-co-o-anisidine)/chitosan composite films

dc.contributor.authorYalcinkaya, Suleyman
dc.contributor.authorCakmak, Didem
dc.date.accessioned2024-09-18T20:55:34Z
dc.date.available2024-09-18T20:55:34Z
dc.date.issued2017
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractIn this study, poly(pyrrole-co-o-anisidine)/chitosan composite films were electrochemically synthesized in various monomers feed ratio (pyrrole: o-anisidine; 9:1, 7:3,1:1, 3:7 and 1:9) of pyrrole and o-anisidine on the platinum electrode. Electrochemical synthesis of the composite films was carried out via cyclic voltammetry technique. They were characterized by FT-IR, cyclic voltammetry, SEM micrographs, digital images, TGA and DSC techniques. The SEM results indicated that the particle size of the composite decreased with increasing o-anisidine ratio and the films became more likely to be smooth morphology. The TGA results proved that the film of the composite with 1:1 ratio showed highest final degradation temperature and lowest weight loss (83%) compared to copolymer and 9:1 1:9 composite films. The 1:1 composite film had higher thermal stability than copolymer and the other composite films (9:1 1:9). Meanwhile, electrochemical studies exhibited that the 1/9 composite film had good electrochemical stability as well. (C) 2017 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T523]en_US
dc.description.sponsorshipThis study has been supported by the Scientific and Technological Research Council of Turkey (TUBITAK). (Project number: 112T523).en_US
dc.identifier.doi10.1016/j.molstruc.2017.01.040
dc.identifier.endpage43en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85009961769en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage32en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.01.040
dc.identifier.urihttps://hdl.handle.net/20.500.12483/11931
dc.identifier.volume1135en_US
dc.identifier.wosWOS:000395604700005en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPyrroleen_US
dc.subjecto-anisidineen_US
dc.subjectChitosanen_US
dc.subjectCompositeen_US
dc.subjectElectrochemical synthesisen_US
dc.titleElectrochemical synthesis of poly(pyrrole-co-o-anisidine)/chitosan composite filmsen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ N/A ]
İsim:
Tam Metin / Full Text
Boyut:
5.88 MB
Biçim:
Adobe Portable Document Format