Electrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrode

dc.contributor.authorCakmak, D.
dc.contributor.authorBulut, T.
dc.contributor.authorUzun, D.
dc.date.accessioned2024-09-18T20:56:50Z
dc.date.available2024-09-18T20:56:50Z
dc.date.issued2020
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractThis present study describes a pencil graphite electrode surface covered with Cu(II) and Fe(III) complexes based on Salophen derivative Schiff bases in acetonitrile solution containing LiClO4 as a supporting electrolyte. Cyclic voltammetry method was used for the surface modification procedure with 25 cycle at a sweep rate of 50 mV s(-1). Some characterization methods were used to identify of the prepared modified surfaces including cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), Ultraviolet-visible Spectroscopy (UV-Vis), and Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM/SEM-EDX). The catalytic activity of these modified surfaces on the electrochemical oxidation of catechol (CC) was investigated and they compared with each other. The results demonstrated that these modified electrodes showed perfect electrocatalytic activity on the catechol determination, however the modified electrode prepared with the Cu(II) complex has higher catalytic activity than this prepared with the Fe(III) complex thanks to its the lower detection limit.en_US
dc.description.sponsorshipScientific Research Projects Committee of Mustafa Kemal University [:15101]en_US
dc.description.sponsorshipThis study is supported by Scientific Research Projects Committee of Mustafa Kemal University (Project number:15101).en_US
dc.identifier.doi10.1002/elan.202000053
dc.identifier.endpage1570en_US
dc.identifier.issn1040-0397
dc.identifier.issn1521-4109
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85082928257en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1559en_US
dc.identifier.urihttps://doi.org/10.1002/elan.202000053
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12107
dc.identifier.volume32en_US
dc.identifier.wosWOS:000522300600001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofElectroanalysisen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSalophen derivativeen_US
dc.subjectCu(II) and Fe(III) complexesen_US
dc.subjectcharacterization methodsen_US
dc.subjectvoltammetric investigationen_US
dc.titleElectrocatalytic Investigations of Cu(II) and Fe(III) Complexes of Salophen Derivative Schiff Bases on the Pencil Graphite Electrodeen_US
dc.typeArticleen_US

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