A novel study on ZnO nanostructures: coumarin effect

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Date

2012

Journal Title

Journal ISSN

Volume Title

Publisher

Taylor & Francis Ltd

Access Rights

info:eu-repo/semantics/closedAccess

Abstract

This novel study reports the behaviour of coumarin during the ZnO chemical bath deposition (CBD) process. Scanning electron microscopy studies revealed that grain sizes of the ZnO nanostructures get smaller and become more uniform in size with increasing coumarin content. Length-to-diameter ratio of the structures increased with the incorporation of coumarin. From the X-Ray diffraction results, with increasing coumarin content, significant decrease in grain sizes was determined. It was found that resistivity values of the structures increased with increasing coumarin content. This increase is attributed with a decrease in carrier concentration originated by carrier traps at the grain boundaries. Through slopes of lnR versus 1/T curves, impurity level ionization energy values were calculated as 0.16, 0.06 eV; 0.11, 0.02 eV; and 0.08, 0.06 eV for the structure growth in the solutions containing 0, 1 and 5 at.% coumarin, respectively.

Description

Keywords

coumarin, chemical bath deposition, ZnO

Journal or Series

Philosophical Magazine Letters

WoS Q Value

Q3

Scopus Q Value

Q3

Volume

92

Issue

6

Citation