Effects of the sulfurization temperature on sol gel-processed Cu2ZnSnS4 thin films

dc.authoridCetinkaya, Samed/0000-0002-7476-9467
dc.authoridKahraman, suleyman/0000-0002-7730-6353
dc.contributor.authorKahraman, S.
dc.contributor.authorCetinkaya, S.
dc.contributor.authorPodlogar, M.
dc.contributor.authorBernik, S.
dc.contributor.authorCetinkara, H. A.
dc.contributor.authorGuder, H. S.
dc.date.accessioned2024-09-18T20:20:09Z
dc.date.available2024-09-18T20:20:09Z
dc.date.issued2013
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractAs a promising and alternative solar absorber material, the copper zinc tin sulfide compound (Cu2ZnSnS4) has been drawing attention in recent years for the production of cheap thin-film solar cells owing to the high natural abundance and non-toxicity of all the constituents, a tunable direct-band-gap energy and a large optical absorption coefficient. In addition, to overcome the problem of expensive vacuum-based methods, solution-based approaches are being developed for Cu2ZnSnS4 deposition. In this study, we have produced Cu2ZnSnS4 thin films via the sol gel technique and subsequent sulfurization. The effects of the sulfurization temperature on the structural, morphological, compositional and optical properties of the films were investigated. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of phase-pure CZTS films. The crystallinity of the films increased with an increasing sulfurization temperature. From the surface images and the results of the composition analysis, it was found that the films are uniform, composed of homogenously distributed grains and have compositions with Cu deficit. The values of the optical absorption coefficients for the films were found to be 10(4) cm(-1) based on absorbance spectroscopy. The optical band-gap values were estimated to be between 1.32 and 2.27 eV depending on the sulfurization temperature. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All rights reserved.en_US
dc.description.sponsorshipScientific Research Commission of Mustafa Kemal University [1204D0102]; Slovenian Research Agency [P2-0084-0106/04]; Student Mobility of the European Commission's Lifelong Learning Programme (LLP)en_US
dc.description.sponsorshipThis study was financially supported by Scientific Research Commission of Mustafa Kemal University (Project no. 1204D0102). The authors also acknowledge the financial support of the Slovenian Research Agency (Program Contract no. P2-0084-0106/04) and Student Mobility of the European Commission's Lifelong Learning Programme (LLP).en_US
dc.identifier.doi10.1016/j.ceramint.2013.05.039
dc.identifier.endpage9292en_US
dc.identifier.issn0272-8842
dc.identifier.issn1873-3956
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84883765473en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage9285en_US
dc.identifier.urihttps://doi.org/10.1016/j.ceramint.2013.05.039
dc.identifier.urihttps://hdl.handle.net/20.500.12483/10077
dc.identifier.volume39en_US
dc.identifier.wosWOS:000325835100097en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofCeramics Internationalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectFilmsen_US
dc.subjectSol-gel processen_US
dc.subjectSpectroscopyen_US
dc.subjectX-ray methodsen_US
dc.titleEffects of the sulfurization temperature on sol gel-processed Cu2ZnSnS4 thin filmsen_US
dc.typeArticleen_US

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