Electrochromism of W-In oxide thin films: Implications for cycling durability

Yükleniyor...
Küçük Resim

Tarih

2020

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Sa

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Electrochromic W oxide and W-In oxide thin films were prepared by dual-target reactive DC magnetron sputtering and were cycled voltammetrically in an electrolyte of lithium perchlorate in propylene carbonate. Film degradation was investigated for up to 500 cycles in the voltage ranges 1.5-4.0, 1.7-4.0 and 2.0-4.0 V vs. Li/Li+, and optical transmittance was recorded concurrently. Indium doping was found to be unambiguously detrimental to electrochromic cycling durability, which resolves an outstanding issue related to recently discovered unprecedented durability of potentiostatically pretreated W oxide films backed by In2O3:Sn and gives strong support in favor of beneficial effects of solid-electrolyte interfacial layers.

Açıklama

Anahtar Kelimeler

Electrochromism, Thin films, Tungsten oxide, Indium oxide, Sputter deposition, Cycling durability

Kaynak

Thin Solid Films

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

697

Sayı

Künye