Electrochromism of W-In oxide thin films: Implications for cycling durability
Yükleniyor...
Dosyalar
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Electrochromic W oxide and W-In oxide thin films were prepared by dual-target reactive DC magnetron sputtering and were cycled voltammetrically in an electrolyte of lithium perchlorate in propylene carbonate. Film degradation was investigated for up to 500 cycles in the voltage ranges 1.5-4.0, 1.7-4.0 and 2.0-4.0 V vs. Li/Li+, and optical transmittance was recorded concurrently. Indium doping was found to be unambiguously detrimental to electrochromic cycling durability, which resolves an outstanding issue related to recently discovered unprecedented durability of potentiostatically pretreated W oxide films backed by In2O3:Sn and gives strong support in favor of beneficial effects of solid-electrolyte interfacial layers.
Açıklama
Anahtar Kelimeler
Electrochromism, Thin films, Tungsten oxide, Indium oxide, Sputter deposition, Cycling durability
Kaynak
Thin Solid Films
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
697