Synthesis and Characterization of Poly(Aniline-co-o-Aminoaniline)
| dc.contributor.author | Yalcinkaya, Suleyman | |
| dc.contributor.author | Colak, Nureddin | |
| dc.date.accessioned | 2024-09-18T20:54:20Z | |
| dc.date.available | 2024-09-18T20:54:20Z | |
| dc.date.issued | 2012 | |
| dc.department | Hatay Mustafa Kemal Üniversitesi | en_US |
| dc.description.abstract | Poly(aniline-co-o-nitroaniline) co-polymer was synthesized by a chemical oxidation process using ammonium peroxydisulfate. The reaction was carried out in aqueous HCl solution with aniline and o-nitroaniline in a molar ratio of 4:1. Although o-nitroaniline did not homo-polymerize, the co-polymer of aniline with o-nitroaniline was readly synthesized. Poly(aniline-co-o-aminoaniline) was prepared by reducing poly(aniline-co-o-nitroaniline) in Fe catalyst at 90-100 degrees C. Co-polymer samples were characterized by FT-IR, UV-Vis and H-1-NMR spectroscopy, DSC and cyclic voltammetry. Also, solubility of the co-polymer samples was investigated with tetrahydrofuran (THF), dimethylsulfoxide (DMSO), dimethylformamide (DMF), N-methylpyrrolidone (NMP), chloroform, acetone and pyridine. DMF and DMSO were found as the best solvents for poly(aniline-co-o-aminoaniline) and poly(aniline-co-o-nitroaniline). In addition, poly(aniline-co-o-nitroaniline) was more soluble in DMF and DMSO than poly(aniline-co-o-aminoaniline). The DSC results and cyclic voltammetry studies showed that co-polymer samples had good thermal stability and electroactivity. (C) Koninklijke Brill NV, Leiden, 2012 | en_US |
| dc.identifier.doi | 10.1163/156855511X615038 | |
| dc.identifier.endpage | 157 | en_US |
| dc.identifier.issn | 1385-772X | |
| dc.identifier.issn | 1568-5551 | |
| dc.identifier.issue | 2 | en_US |
| dc.identifier.scopus | 2-s2.0-84857806723 | en_US |
| dc.identifier.scopusquality | Q3 | en_US |
| dc.identifier.startpage | 147 | en_US |
| dc.identifier.uri | https://doi.org/10.1163/156855511X615038 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12483/11755 | |
| dc.identifier.volume | 15 | en_US |
| dc.identifier.wos | WOS:000302918900004 | en_US |
| dc.identifier.wosquality | Q3 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Taylor & Francis Ltd | en_US |
| dc.relation.ispartof | Designed Monomers and Polymers | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Poly(aniline-co-o-nitroaniline) | en_US |
| dc.subject | poly(aniline-co-o-aminoaniline) | en_US |
| dc.subject | co-polymer | en_US |
| dc.subject | synthesis | en_US |
| dc.subject | characterization | en_US |
| dc.title | Synthesis and Characterization of Poly(Aniline-co-o-Aminoaniline) | en_US |
| dc.type | Article | en_US |
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