Crystal structure of an unsymmetrical Schiff base, immobilization of its cobalt and manganese complexes on a silica support, and catalytic studies

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dc.authoridgonul, ilyas/0000-0002-7697-3613
dc.authoridDEMETGUL, CAHIT/0000-0003-1559-7279
dc.contributor.authorDurak, Damla
dc.contributor.authorDelikanli, Anil
dc.contributor.authorDemetgul, Cahit
dc.contributor.authorKani, Ibrahim
dc.contributor.authorSerin, Selahattin
dc.date.accessioned2024-09-18T21:02:58Z
dc.date.available2024-09-18T21:02:58Z
dc.date.issued2013
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractAn unsymmetrical tetradentate Schiff base (H2L) was synthesized by the reaction of 3-methoxysalicylaldehyde, o-phenylenediamine, and salicylaldehyde in EtOH. H2L was characterized by single-crystallographic X-ray analysis. Its Co(II) and Mn(III) complexes ([CoL] and [MnLCl]) were prepared and immobilized on 3-aminopropyltriethoxysilane functionalized silica gel. The immobilized materials were found to be efficient catalysts for epoxidation of styrene in the presence of tert-BuOOH in acetonitrile at 40 A degrees C. The catalysts can be reused several times without significant loss of performance.en_US
dc.description.sponsorshipScientific and Technological Research Council (TUBITAK) [109T416]en_US
dc.description.sponsorshipThe authors thank the Scientific and Technological Research Council (TUBITAK) for financial support (Project Number 109T416). Also, the authors are grateful to Anadolu University and the Medicinal Plants and Medicine research Centre of Anadolu University, Eskisehir, Turkey, for the use of X-ray Diffractometer.en_US
dc.identifier.doi10.1007/s11243-012-9678-0
dc.identifier.endpage206en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84876492497en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage199en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-012-9678-0
dc.identifier.urihttps://hdl.handle.net/20.500.12483/13174
dc.identifier.volume38en_US
dc.identifier.wosWOS:000316063600011en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntimicrobial Activityen_US
dc.subjectMetal-Complexesen_US
dc.subjectLigandsen_US
dc.subjectEpoxidationen_US
dc.subjectCopperen_US
dc.subjectOlefinsen_US
dc.subjectZincen_US
dc.titleCrystal structure of an unsymmetrical Schiff base, immobilization of its cobalt and manganese complexes on a silica support, and catalytic studiesen_US
dc.typeArticleen_US

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