Silicon Acetal Metathesis Polymerization

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dc.authoridSahmetlioglu, Ertugrul/0000-0002-7324-0385
dc.authoridGokturk, ersen/0000-0001-6742-2847
dc.contributor.authorSahmetlioglu, Ertugrul
dc.contributor.authorHa Thi Hoang Nguyen
dc.contributor.authorNsengiyumva, Olivier
dc.contributor.authorGokturk, Ersen
dc.contributor.authorMiller, Stephen A.
dc.date.accessioned2024-09-18T21:03:15Z
dc.date.available2024-09-18T21:03:15Z
dc.date.issued2016
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractA kinetic study revealed that the acid-catalyzed (p-TSA) equilibration of Me2Si(OMe)(2) and Me2Si(OEt)(2), forming Me2Si(OEt)OMe, is established in 300 min in benzene at room temperature. This silicon acetal metathesis reaction is exploited for the step-growth polymerization of bissilicon acetals (MeOSiMe2OROSiMe2OMe) with metathetical loss of Me2Si(OMe)(2). Thus, a convenient and generalized silicon acetal metathesis polymerization (SAMP) method is introduced as the acid-catalyzed copolymerization of a diol (HOROH) and Me2Si(OMe)(2), driven by elimination of methanol and/or Me2Si(OMe)(2). SAMP constitutes an effective and powerful strategy for manipulating the most common bond in the Earth's crust, the silicon oxygen bond.en_US
dc.description.sponsorshipNational Science Foundation [CHE-1305794]; University of Florida; Scientific and Technological Research Council of Turkey (TUBITAK); Turkish Ministry of National Education; Division Of Chemistry; Direct For Mathematical & Physical Scien [1305794] Funding Source: National Science Foundationen_US
dc.description.sponsorshipThis research was supported by the National Science Foundation (CHE-1305794) and the University of Florida. E.S. thanks the Scientific and Technological Research Council of Turkey (TUBITAK) for his Tubitak 2219 international postdoctoral research fellowship. E.G. graciously acknowledges the Turkish Ministry of National Education for his Ph.D. scholarship.en_US
dc.identifier.doi10.1021/acsmacrolett.6b00095
dc.identifier.endpage470en_US
dc.identifier.issn2161-1653
dc.identifier.issue4en_US
dc.identifier.pmid35607239en_US
dc.identifier.startpage466en_US
dc.identifier.urihttps://doi.org/10.1021/acsmacrolett.6b00095
dc.identifier.urihttps://hdl.handle.net/20.500.12483/13327
dc.identifier.volume5en_US
dc.identifier.wosWOS:000374716700009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofAcs Macro Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiorenewable Diolsen_US
dc.subjectOlefinen_US
dc.subjectCopolymersen_US
dc.titleSilicon Acetal Metathesis Polymerizationen_US
dc.typeArticleen_US

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