Schiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styrene

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dc.authoridgonul, ilyas/0000-0002-7697-3613
dc.authoridDEMETGUL, CAHIT/0000-0003-1559-7279
dc.contributor.authorDemetgul, Cahit
dc.contributor.authorDelikanli, Anil
dc.contributor.authorSaribiyik, Oguz Yunus
dc.contributor.authorKarakaplan, Muruvvet
dc.contributor.authorSerin, Selahattin
dc.date.accessioned2024-09-18T20:56:51Z
dc.date.available2024-09-18T20:56:51Z
dc.date.issued2012
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractIn this paper, Schiff base monomers having double azomethine groups, N,N'-bis(4-hydroxybenzylidene)1, 4-phenylenediamine (M-1) and N,N'-bis(4-hydroxysalicylidene)1,4-phenylenediamine (M-2), were prepared by a common condensation reaction between 4-hydroxybenzaldehyde and 4-hydroxysalicylaldehyde with 1,4-phenylenediamine, respectively. The new Schiff base polymers, poly(N,N'-bis(4-hydroxybenzylidene)1,4-phenylenediamine) (P-1) and poly(N,N'-bis(4-hydroxysalicylidene)1,4-phenylenediamine) (P-2) were synthesized from the oxidative polycondensation of monomers with NaOCl in an aqueous alkaline medium. The characterization of synthesized monomers and polymers was carried out by FT-IR, UV-Vis, H-1-NM, C-13-NMR and elemental analysis. The new polymer-metal complexes were prepared by using polymers and Co(II), Mn(II) and Ru(III) metal salts. Thermal properties of the compounds were studied by TG-DTA techniques. In addition, the catalytic properties of the polymers and their metal complexes were investigated in epoxidation reactions of styrene. The results of the catalysis studies were monitored by GC-MS. (C) Koninklijke Brill NV, Leiden, 2012en_US
dc.description.sponsorshipScientific and Technological Research Council (Tubitak) [106 T 365]en_US
dc.description.sponsorshipThe authors thank The Scientific and Technological Research Council (Tubitak) for financial support (Project No. 106 T 365).en_US
dc.identifier.doi10.1163/156855511X606164
dc.identifier.endpage91en_US
dc.identifier.issn1385-772X
dc.identifier.issn1568-5551
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84866283906en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage75en_US
dc.identifier.urihttps://doi.org/10.1163/156855511X606164
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12133
dc.identifier.volume15en_US
dc.identifier.wosWOS:000297806800006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofDesigned Monomers and Polymersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff base polymeren_US
dc.subjectoxidative polycondensationen_US
dc.subjectpolymer-metal complexesen_US
dc.subjectcatalysten_US
dc.subjectstyrene epoxidationen_US
dc.titleSchiff Base Polymers Obtained by Oxidative Polycondensation and Their Co(II), Mn(II) and Ru(III) Complexes: Synthesis, Characterization and Catalytic Activity in Epoxidation of Styreneen_US
dc.typeArticleen_US

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