Synthesis and characterization of a Schiff base derived from 2-aminobenzylamine and its Cu(II) complex: electropolymerization of the complex on a platinum electrode

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dc.authoridDEMETGUL, CAHIT/0000-0003-1559-7279
dc.authoridtimur, mahir/0000-0001-5914-607X
dc.contributor.authorDemetgul, Cahit
dc.contributor.authorDeletioglu, Didem
dc.contributor.authorKaraca, Filiz
dc.contributor.authorYalcinkaya, Sueleyman
dc.contributor.authorTimur, Mahir
dc.contributor.authorSerin, Selahattin
dc.date.accessioned2024-09-18T19:47:57Z
dc.date.available2024-09-18T19:47:57Z
dc.date.issued2010
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractA precursor (H3A) was synthesized by the mono condensation of 2-aminobenzylamine with salicylaldehyde and then a tetradentade Schiff-base ligand (H2L) prepared by using H3A and 3-methoxysalicylaldehyde. The copper(II) complex of this new ligand was prepared and characterized by elemental analysis, electronic absorption, Fourier transform infrared (FT-IR), and magnetic susceptibility. For the ligand, 1H- and 13C-NMR and liquid chromatography mass spectrometry (LC-MS) spectra were obtained. The tetradentate ligand is coordinated to Cu(II) through the phenolic oxygen and azomethine nitrogen. The use of this metal complex in the preparation of a modified electrode is also described. CuL was electropolymerized on a platinum electrode surface in a 0.1 mol dm-3 solution of lithium perchlorate in acetonitrile by cyclic voltammetry between 0 and 1.6 V versus Ag/Ag+. Electrochemical properties of the electroactive polymeric film have been investigated and a surface confined polymerization mechanism was proposed.en_US
dc.description.sponsorshipCukurova University in Turkey [FEF2009YL-3]; Department of Chemistry of Mustafa Kemal Universityen_US
dc.description.sponsorshipThe authors are grateful to the Science Research Fund of the Cukurova University in Turkey for supporting this study (project no. FEF2009YL-3) and to the Department of Chemistry of Mustafa Kemal University for allowing the use of its laboratory facilities.en_US
dc.identifier.doi10.1080/00958972.2010.496852
dc.identifier.endpage2191en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-77954909963en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage2181en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2010.496852
dc.identifier.urihttps://hdl.handle.net/20.500.12483/7249
dc.identifier.volume63en_US
dc.identifier.wosWOS:000280283400016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Aminobenzylamineen_US
dc.subjectSchiff baseen_US
dc.subjectCopper(II) complexen_US
dc.subjectElectropolymerizationen_US
dc.subjectModified electrodeen_US
dc.titleSynthesis and characterization of a Schiff base derived from 2-aminobenzylamine and its Cu(II) complex: electropolymerization of the complex on a platinum electrodeen_US
dc.typeArticleen_US

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