A comparative study of Cu2ZnSnS4 thin films growth by successive ionic layer adsorption-reaction and sol-gel methods

dc.authoridCetinkaya, Samed/0000-0002-7476-9467
dc.authoridKahraman, suleyman/0000-0002-7730-6353
dc.contributor.authorKahraman, S.
dc.contributor.authorCetinkaya, S.
dc.contributor.authorCetinkara, H. A.
dc.contributor.authorGuder, H. S.
dc.date.accessioned2024-09-18T20:59:23Z
dc.date.available2024-09-18T20:59:23Z
dc.date.issued2014
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractOwing to the high natural abundance and non-toxicity of all the constituents, the copper-zinc-tin-sulfide compound has been attracting attention in recent years for the production of cheap solar absorber materials. Solution-based low-cost approaches are being developed for the deposition of this compound. In this comparative study, we have investigated Cu2ZnSnS4 thin films prepared by using successive ionic layer adsorption-reaction and sol-gel methods. X-ray diffraction studies indicated the polycrystalline nature of the films. No secondary phases were observed. The sol-gel grown Cu2ZnSnS4 film was found to have smaller crystallite size and higher microstrain and dislocation density values. Phase purity and good crystalline quality of the studied films were proved through the Raman studies. From the scanning electron microscopy images, sol-gel grown Cu2ZnSnS4 film was found to have more homogenous and smooth morphology. Possible chemical formula of the films was determined. The optical absorption of the sol-gel grown film covered a wider wavelength range by means of absorbing more visible photons. The optical band gap values were estimated to be 1.45 and 1.40 eV for the successive ionic layer adsorption-reaction and sol-gel grown samples, respectively. It was concluded that both methods are effective and can be used to produce high-quality Cu2ZnSnS4 thin films for cheap and green solar cell applications. (C) 2013 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipScientific Research Commission of Mustafa Kemal University [1204D0102]en_US
dc.description.sponsorshipWe would like to thank Assist. Prof. Slavko Bernik for helpful discussions and assistance during the study and to Ms. Mateja Podlogar for her support during the characterizations. The financial support from Scientific Research Commission of Mustafa Kemal University (Project No: 1204D0102) is greatly appreciated.en_US
dc.identifier.doi10.1016/j.tsf.2013.10.035
dc.identifier.endpage39en_US
dc.identifier.issn0040-6090
dc.identifier.scopus2-s2.0-84890311401en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage36en_US
dc.identifier.urihttps://doi.org/10.1016/j.tsf.2013.10.035
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12552
dc.identifier.volume550en_US
dc.identifier.wosWOS:000328499700006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofThin Solid Filmsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThin filmsen_US
dc.subjectCopper zinc tin sulfideen_US
dc.subjectSol-gelen_US
dc.subjectSuccessive ionic layer adsoprtion-reactionen_US
dc.subjectSulfurizationen_US
dc.titleA comparative study of Cu2ZnSnS4 thin films growth by successive ionic layer adsorption-reaction and sol-gel methodsen_US
dc.typeArticleen_US

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