Poly(o-anisidine) on brass
Yükleniyor...
Tarih
2008
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Korean Inst Chem Engineers
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The electrochemical synthesis of poly(o-anisidine) (POA) was achieved on brass (CuZn) electrode by applying two scan rates (50 and 20 mVs(-1)). The synthesized polymer films were strongly adherent and homogeneous in both cases. Their corrosion performance was investigated by AC impedance spectroscopy (EIS) technique, anodic polarization plots and open circuit potential-time curves, in 3.5% NaCl solution. It was clearly seen that poly(o-anisidine) films provided a significant physical protection for longer exposure time. It was shown that polymer film coated at high scan rate (CuZn/POA-H) exhibited better barrier property against the attack of corrosive agents when compared with polymer film obtained at low scan rate (CuZn/POA-L). It was found out that poly(o-anisidine) film synthesized at high scan rate caused a significant increase in corrosion resistance by its catalytic behavior on formation of protective oxide layers on the surface in longer time.
Açıklama
Anahtar Kelimeler
coatings, corrosion, brass, poly(o-anisidine), AC impedance
Kaynak
Korean Journal of Chemical Engineering
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
25
Sayı
4
