Asymmetric Henry reactions catalyzed by metal complexes of chiral oxazoline based ligands

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dc.authoridYUKSEKDANACI, SEDA/0000-0003-0387-8591
dc.contributor.authorAydin, A. Ebru
dc.contributor.authorYuksekdanaci, Seda
dc.date.accessioned2024-09-18T21:03:10Z
dc.date.available2024-09-18T21:03:10Z
dc.date.issued2013
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstractChiral oxazolines have been synthesized from norephedrine and pyrrole nitrile or benzoyl chloride and applied to the catalytic asymmetric Henry reactions of p-nitro aldehydes with nitromethane to provide beta-hydroxy nitroalkanols in high conversion (up to 92%). The reaction was then optimized in terms of the metal, solvent, temperature, and amount of chiral ligand. The corresponding catalyst with Cu(OTf)(2) and isopropanol as the solvent gave the best enantioselectivities (up to 84% ee) of the corresponding beta-nitroalkanol for p-nitrobenzaldehyde. (C) 2012 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific Research Commission of Mustafa Kemal University [04Y0127]en_US
dc.description.sponsorshipThis research (04Y0127) is financially supported by the Scientific Research Commission of Mustafa Kemal University. The authors would like to thank the Scientific Research Commission of Mustafa Kemal University.en_US
dc.identifier.doi10.1016/j.tetasy.2012.11.022
dc.identifier.endpage22en_US
dc.identifier.issn0957-4166
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84872311156en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage14en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetasy.2012.11.022
dc.identifier.urihttps://hdl.handle.net/20.500.12483/13288
dc.identifier.volume24en_US
dc.identifier.wosWOS:000314488700003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron-Asymmetryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectEnantioselective Nitroaldol Reactionen_US
dc.subjectMicrowave-Assisted Synthesisen_US
dc.subjectOne-Pot Conversionen_US
dc.subjectBis(Oxazoline) Ligandsen_US
dc.subjectEfficient Synthesisen_US
dc.subjectFacile Synthesisen_US
dc.subjectAmino-Alcoholsen_US
dc.subjectSolvent-Freeen_US
dc.subjectAldehydesen_US
dc.subject2-Imidazolinesen_US
dc.titleAsymmetric Henry reactions catalyzed by metal complexes of chiral oxazoline based ligandsen_US
dc.typeArticleen_US

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