Synthesis, characterization, and optical studies of pentoxy-substituted tetrakis(pentafluorobenzyloxy)phthalocyanines

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Küçük Resim

Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor & Francis Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The synthesis and characterization of peripherally 2,3,5,6-tetrafluoro-4-pentoxy-benzyloxy-substituted metal-free and metallo (Zn(II) and Co(II)) phthalocyanines are described in this study. Aggregation properties of these phthalocyanines were studied in the concentration range of 1x10(-5)-1x10(-6)M in tetrahydrofuran. Thin films of phthalocyanines were prepared by spin-coating technique. The spectrophotometric measurements of transmittance spectra were carried out in the wavelength range of 200-1000nm. Optical band gaps of phthalocyanine thin films were also calculated. Surface morphologies and thickness of the films were examined by Scanning Electron Microscopy. Results show that film thickness can be changed significantly depending on the type of metal in the phthalocyanine.

Açıklama

Anahtar Kelimeler

Phthalocyanine, fluorinated groups, spin coating, thin film, optical properties

Kaynak

Journal of Coordination Chemistry

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

71

Sayı

15

Künye