Synthesis of salen-type Schiff base metal complexes, electropolymerization on graphite electrode surface and investigation of electrocatalytic effects
Yükleniyor...
Dosyalar
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
2-Aminobenzylamine-based unsymmetrical salen-type Schiff base and its Cu (II), Ni (II), Co (II) and Fe (III) metal complexes were synthesized and their structures were investigated by various spectroscopic methods. The electropolymerization of the synthesized metal complexes were achieved on the graphite electrode. The electropolymerization process was conducted by cyclic voltammetry (CV) in a 0.15 M LiClO4/Acetonitrile as supporting electrolyte medium. Characterization of the polymer coated electrodes were carried out by CV, SEM, EDX and UV-Vis techniques. The electrocatalytic activities of graphite electrodes modified with Schiff-base metal complex were investigated in the determination of compounds such as Dopamine (DA), Catechol (CC), Cysteine (Cys) and Uric Acid (UA). These studies showed that the salen-type Schiff base-Ni(II)-modified graphite electrode gave the best result in the determination of catechol and dopamine. Square wave voltammetry showed a linear response in the range of 0.09-0.35 mu M and 0.22-0.58 mu M with LoD of 0.03 mu M and 0.06 mu M for CC and DA, respectively.
Açıklama
Anahtar Kelimeler
Salen-type Schiff base, Metal complexes, Grafit electrode, Electropolymerization, Electrocatalytic studies
Kaynak
Journal of Electroanalytical Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
808
