Synthesis of salen-type Schiff base metal complexes, electropolymerization on graphite electrode surface and investigation of electrocatalytic effects

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dc.authoridDEMETGUL, CAHIT/0000-0003-1559-7279
dc.contributor.authorCakmak, Didem
dc.contributor.authorCakran, Sinem
dc.contributor.authorYalcinkaya, Suleyman
dc.contributor.authorDemetgul, Cahit
dc.date.accessioned2024-09-18T20:56:49Z
dc.date.available2024-09-18T20:56:49Z
dc.date.issued2018
dc.departmentHatay Mustafa Kemal Üniversitesien_US
dc.description.abstract2-Aminobenzylamine-based unsymmetrical salen-type Schiff base and its Cu (II), Ni (II), Co (II) and Fe (III) metal complexes were synthesized and their structures were investigated by various spectroscopic methods. The electropolymerization of the synthesized metal complexes were achieved on the graphite electrode. The electropolymerization process was conducted by cyclic voltammetry (CV) in a 0.15 M LiClO4/Acetonitrile as supporting electrolyte medium. Characterization of the polymer coated electrodes were carried out by CV, SEM, EDX and UV-Vis techniques. The electrocatalytic activities of graphite electrodes modified with Schiff-base metal complex were investigated in the determination of compounds such as Dopamine (DA), Catechol (CC), Cysteine (Cys) and Uric Acid (UA). These studies showed that the salen-type Schiff base-Ni(II)-modified graphite electrode gave the best result in the determination of catechol and dopamine. Square wave voltammetry showed a linear response in the range of 0.09-0.35 mu M and 0.22-0.58 mu M with LoD of 0.03 mu M and 0.06 mu M for CC and DA, respectively.en_US
dc.description.sponsorshipTechnological Research Council of Turkey [TUBITAK-112T305]en_US
dc.description.sponsorshipWe would like to thank The Scientific and Technological Research Council of Turkey (TUBITAK-112T305) for its financial support.en_US
dc.identifier.doi10.1016/j.jelechem.2017.11.058
dc.identifier.endpage74en_US
dc.identifier.issn1572-6657
dc.identifier.issn1873-2569
dc.identifier.scopus2-s2.0-85035785736en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage65en_US
dc.identifier.urihttps://doi.org/10.1016/j.jelechem.2017.11.058
dc.identifier.urihttps://hdl.handle.net/20.500.12483/12097
dc.identifier.volume808en_US
dc.identifier.wosWOS:000423650000010en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Electroanalytical Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSalen-type Schiff baseen_US
dc.subjectMetal complexesen_US
dc.subjectGrafit electrodeen_US
dc.subjectElectropolymerizationen_US
dc.subjectElectrocatalytic studiesen_US
dc.titleSynthesis of salen-type Schiff base metal complexes, electropolymerization on graphite electrode surface and investigation of electrocatalytic effectsen_US
dc.typeArticleen_US

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